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Ionic Solvation in Aqueous and Nonaqueous Solutions
Authors:Hitoshi Ohtaki
Institution:(1) Department of Physics and Postgraduate Institute of Science, University of Peradeniya, Peradeniya, Sri Lanka;(2) Department of Chemistry, Technical University of Denmark, DK-2800 Lyngby, Denmark
Abstract: The history of studies on ionic solvation is briefly reviewed, and structural and dynamic properties of solvated ions in aqueous and nonaqueous solutions are discussed. An emphasis is placed on ionic solvation in nonaqueous mixed solvents in which preferential solvation of ions takes place. A new parameter for expressing the degree of preferential solvation of an ion is proposed.
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