| 对甲苯磺酰甘氨酸构建的鼓型有机锡簇合物的合成与晶体结构(英) |
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| 引用本文： | 张春华,陈满生,邝代治,邓奕芳,陈志敏,余润兰,杨颖群. 对甲苯磺酰甘氨酸构建的鼓型有机锡簇合物的合成与晶体结构(英)[J]. 无机化学学报, 2005, 21(9): 1386-1388 |
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| 作者姓名： | 张春华 陈满生 邝代治 邓奕芳 陈志敏 余润兰 杨颖群 |
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| 作者单位： | 衡阳师范学院化学与材料科学系,衡阳,421008 |
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| 基金项目： | 湖南省自然科学基金资助项目，衡阳师范学院科研启动基金(No.2004D16)资助项目 |
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| 摘 要： | The title complex [ nBuSn(O)(tsglyO)]6·6CHCl3 (tsglyO=N-p-tolysulfonyl-glycinate monoanion) was synthesized by the reaction of nBuSn(O)OH with N-p-tolysulfonyl-glycine in 1∶1 molar ratio. The complex was characterized by IR, 1H NMR spectra and elemental analysis. The crystal structure was determined by X-ray diffraction method. It crystallizes in rhombohedral system with space group R3. The crystal data are: a=b=2.738 7(4) nm, c=1.446 5(4) nm, α=β=90°, γ=120°, Z=6, Dc=1.726 g·cm-3, F(000)=4 878, V=9.396(3) nm3, R1=0.032 5, wR2=0.089 8. The structure shows a distorted octahedral configuration with six-coordination for the central tin atom. CCDC: 274183.
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| 关 键 词： | 有机锡簇合物； 对甲苯磺酰甘氨酸； 晶体结构 |
| 文章编号： | 1001-4861(2005)09-1386-03 |
| 收稿时间： | 2005-01-07 |
| 修稿时间： | 2005-05-12 |
Synthesis and Crystal Structure of a Drum Organooxotin Cluster Constructed from N-p-tolysulfonyl-glycine |
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| ZHANG Chun-Hu,CHEN Man-Sheng,KUANG Dai-Zhi,DENG Yi-Fang,CHEN Zhi-Min,YU Run-Lan and YANG Ying-Qun. Synthesis and Crystal Structure of a Drum Organooxotin Cluster Constructed from N-p-tolysulfonyl-glycine[J]. Chinese Journal of Inorganic Chemistry, 2005, 21(9): 1386-1388 |
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| Authors: | ZHANG Chun-Hu CHEN Man-Sheng KUANG Dai-Zhi DENG Yi-Fang CHEN Zhi-Min YU Run-Lan YANG Ying-Qun |
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| Affiliation: | Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang 421008,Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang 421008,Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang 421008,Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang 421008,Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang 421008,Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang 421008 and Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang 421008 |
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| Abstract: | The title complex [nBuSn(O)(tsglyO)]6·6CHCl3 (tsglyO=N-p-tolysulfonyl-glycinate monoanion) was syn thesized by the reaction of nBuSn(O)OH with N-p-tolysulfonyl-glycine in 1:1 molar ratio. The complex was characterized by IR, 1H NMR spectra and elemental analysis. The crystal structure was determined by X-ray diffractionmethod. It crystallizes in rhombohedral system with space group R-3. The crystal data are: a=b=2.738 7(4) nm, c= 8. The structure shows a distorted octahedral configuration with six-coordination for the central tin atom. CCDC: 274183. |
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| Keywords: | organooxotin cluster N-p-tolysulfonyl-glycine crystal structure |
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