Reactivity studies of a corrole germanium hydride complex with aldehydes, olefins and alkyl halides |
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| Authors: | Fang Huayi Ling Zhen Brothers Penelope J Fu Xuefeng |
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| Institution: | Beijing National Laboratory for Molecular Sciences, College of Chemistry and Molecular Engineering, Peking University, Beijing, 100871, China. |
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| Abstract: | The tris(pentafluorophenyl) corrole germanium hydride complex (TPFC)Ge-H was prepared by the reduction of (TPFC)Ge-OCH(3) with NaBH(4). The reactivity of (TPFC)Ge-H with series of aldehydes, olefins and alkyl halides to produce α-hydroxy alkyl and alkyl complexes was studied. |
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