Simple routes to bulky silyl-substituted acetylide ligands and examples of V(III), Fe(II), and Mn(II) complexes |
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| Authors: | Yee Gereon M Kowolik Kristin Manabe Shuhei Fettinger James C Berben Louise A |
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| Affiliation: | Department of Chemistry, University of California, Davis, CA 95616, USA. |
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| Abstract: | Synthesis of substituted phenylacetylide ligands 2,6-bis(trimethylsilyl)phenylacetylene (H1) and 2-(triphenylsilyl)phenylacteylene (H2) is reported. Ligand 1 supports tetrahedral complexes of V(III), Fe(II), and Mn(II) (3-5). Complexes 3-5 are high-spin and redox active. |
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