Wilkinson's iridium acetate trimer as a water-oxidation catalyst |
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| Authors: | Parent Alexander R Blakemore James D Brudvig Gary W Crabtree Robert H |
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| Institution: | Yale University, Department of Chemistry, PO Box 208107, New Haven, Connecticut 06520-8107, USA. |
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| Abstract: | The catalytic water-oxidation activity of Wilkinson's iridium acetate trimer (1) has been characterized electrochemically and by using chemical oxidants. We show that 1 can function as an operationally homogeneous water-oxidation catalyst when driven with sodium periodate as a primary oxidant, but rapidly decomposes using Ce(IV) as a primary oxidant. |
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