Synthesis and Structure Characterization of Aqua-(μ_2-carbonato-O,O'''')-(2,2''''-bipyridyl)-copper(Ⅱ) Dihydrate |
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作者姓名: | WANGMing-Shenga bGUOGuo-Conga CAILi-ZhenaZHOUGuo-WeiaHUANGJin-Shunaa(StateKeyLaboratoryofStructuralChemistry FujianInstituteofResearchontheStructureofMatter ChineseAcademyofSciences Fuzhou Fujian350002 China)b(GraduateSchoolofChineseAcademyofSciences Beijing100039 China) |
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作者单位: | WANGMing-Shenga,bGUOGuo-Conga,CAILi-ZhenaZHOUGuo-WeiaHUANGJin-Shunaa(StateKeyLaboratoryofStructuralChemistry,FujianInstituteofResearchontheStructureofMatter,ChineseAcademyofSciences,Fuzhou,Fujian350002,China)b(GraduateSchoolofChineseAcademyofSciences,Beijing100039,China) |
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基金项目: | the National Natural Science Foundation of China (20001007,20131020),Natural Science Foundation of the Chinese Academy of Sciences (KJCX2-H3) and Fujian province (2000F006) |
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摘 要: | 1 INTRODUCTION The class of materials of carbonato metal- organic compounds has received much attention as a consequence of their potential applications in biochemical and environmental protection[1~3]. Many carbonato compounds of Cu2+, Co3+ and Zn2+ etc. have been studied[4~6]. The carbonate anion is a versatile bridging ligand, which can bind metal cations in different modes to generate mononuclear, binuclear, trinuclear, tetranuclear and even 1D, 2D and 3D structures[4, 7, 8]. We…
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关 键 词: | hydrothermal 2 2'-bipy carbonato copper(Ⅱ)complex hydrogenbonding |
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