| Synthesis and Structure Characterization of Aqua-(μ_2-carbonato-O,O'''')-(2,2''''-bipyridyl)-copper(Ⅱ) Dihydrate |
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| 作者姓名： | WANGMing-Shenga bGUOGuo-Conga CAILi-ZhenaZHOUGuo-WeiaHUANGJin-Shunaa(StateKeyLaboratoryofStructuralChemistry FujianInstituteofResearchontheStructureofMatter ChineseAcademyofSciences Fuzhou Fujian350002 China)b(GraduateSchoolofChineseAcademyofSciences Beijing100039 China) |
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| 作者单位： | WANGMing-Shenga，bGUOGuo-Conga，CAILi-ZhenaZHOUGuo-WeiaHUANGJin-Shunaa(StateKeyLaboratoryofStructuralChemistry，FujianInstituteofResearchontheStructureofMatter，ChineseAcademyofSciences，Fuzhou，Fujian350002，China)b(GraduateSchoolofChineseAcademyofSciences，Beijing100039，China) |
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| 基金项目： | the National Natural Science Foundation of China (20001007，20131020)，Natural Science Foundation of the Chinese Academy of Sciences (KJCX2-H3) and Fujian province (2000F006) |
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| 摘 要： | 1 INTRODUCTION The class of materials of carbonato metal- organic compounds has received much attention as a consequence of their potential applications in biochemical and environmental protection[1～3]. Many carbonato compounds of Cu2+, Co3+ and Zn2+ etc. have been studied[4～6]. The carbonate anion is a versatile bridging ligand, which can bind metal cations in different modes to generate mononuclear, binuclear, trinuclear, tetranuclear and even 1D, 2D and 3D structures[4, 7, 8]. We…
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| 关 键 词： | hydrothermal 2 2'-bipy carbonato copper(Ⅱ)complex hydrogenbonding |
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