Stabilising small clusters: synthesis and characterisation of thermolabile [Gd4F7(15-crown-5)4][AsF6]5.6 SO2 |
| |
| Authors: | Deacon Glen B Evans David J Junk Peter C Lork Enno Mews Rüdiger Zemva Boris |
| |
| Affiliation: | School of Chemistry, Monash University, Victoria, 3800, Australia. Peter.Junk@sci.monash.edu.au. |
| |
| Abstract: | Addition of 15-crown-5 to [GdF(AsF6)2], both dissolved in liquid SO2, and crystallisation at -30 degrees C has led to the isolation of the tetranuclear ionic complex [Gd4F7(15-crown-5)4][AsF6]5.6 SO2 which is stable up to--10 degrees C where SO2 loss leads to loss of crystallinity. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
