Interconversions of heterocycles containing S,N, and O |
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Authors: | S A Vartanyan A S Noravyan V N Zhamagortsyan |
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Institution: | (1) Institute of Organic Chemistry, AS Armenian, SSR |
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Abstract: | On heating with hydrogen sulfide in the presence of sulfuric acid, tetrahydropyran-4-ones (III) and 4-piperidones (II) are converted to the corresponding thiopyranones (I). The anticipated III are obtained by heating I or II in dilute sulfuric acid solution in the presence of mercuric sulfate. Analogously, I and II in aqueous methylamine solution are converted to II;2,3,6-trimethyl-4-pyrone (VII) and 1, 2, 3, 6-tetramethyl-4-pyridonen (VIII) are also interconvertible. |
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