Thermal behaviour of uranium(VI) complexes |
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| Authors: | L. Abate A. Chisari G. Romeo R. Maggiore G. Siracusa |
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| Affiliation: | 1. Facoltà di Scienze, Istituto Dipartimentale di Chimica e Chimica Industriale, Italy
2. Facoltà di Ingegneria, Università di Catania, Viale a. Doria 6, 95125, Catania, Italy
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| Abstract: | The solid-state syntheses of complexes of uranyl acetate dihydrate andN-phenylthiourea have been attempted by heating various stoichiometric mixtures of the reactants directly in a DSC and in a TA apparatus. Both the DSC and the TG results indicate that only the 1∶1 adduct is formed, independently of the molar ratios of the reactants. It appears that the reaction is complete only with a large excess ofN-phenylthiourea, in agreement with IR data. |
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