β-Aluminas and water |
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Authors: | A Marini G Flor V Massarotti V Berbenni R Riccardi |
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Institution: | 1. Centro di Studio per la Termodinamica ed Elettrochimica del Sistemi Salini Fusi e Solidi del C.N.R., Dipartimento di Chimica-Fisica Dell'Università di Pavia, Via Taramelli 16, 27100, Pavia, Italy
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Abstract: | TG, DSC and X-ray measurements were made to characterize the water absorption process by Li (50%) — Na (50%)β-alumina. The equilibrium water content, dehydration enthalpies and lattice parameter values have been determined and compared with those previously obtained for pure Li and Naβ-aluminas. The mixedβ-alumina is shown to be very similar to Liβ-alumina as concerns the dehydration enthalpy and the temperature range in which the dehydration occurs, while it seems to be very similar to Naβ-alumina with respect to the equilibrium water content andc-axis values. |
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