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| 具有平面结构的四齿肼基硫代甲酸苄酯席夫碱镍配合物的合成,晶体结构和三阶非线性光学性质研究 | |
| 引用本文： | 周建豪,王玉晓,陈学太,宋瑛林,翁林红,游效曾.具有平面结构的四齿肼基硫代甲酸苄酯席夫碱镍配合物的合成,晶体结构和三阶非线性光学性质研究[J].无机化学学报,2002,18(5):533-536. |
| 作者姓名： | 周建豪 王玉晓 陈学太 宋瑛林 翁林红 游效曾 |
| 作者单位： | 1. 南京大学配位化学国家重点实验室,配位化学研究所,南京,210093 2. 哈尔滨工业大学应用物理系,哈尔滨,150001 3. 复旦大学化学系,上海,200433 |
| 基金项目： | 国家自然科学基金资助项目(No.20028101)，江苏省自然科学基金资助项目(No.BK99032)~~ |
| 摘 要： | ０IntroductionThereiscurrentlyintenseresearchinterestinde－velopingnewnonlinearmaterialswithhighthird－ordernonlinearopticaleffectsduetotheirpotentialapplica－tionsinanumberofimportanttechnologiesincludingopticalpowerlimitingforsensorprotection，opticalswitches，allopticalsignalprocessingandopticalcom－puting犤１～３犦．Metalcomplexeswithplanar，π－conjugatedtetradentateorbidentateligandareofparticularinterestbecausetheycontainbothelectronsthatarefreetomovewithintheπextendedsystemoftheligand… |
| 关 键 词： | 镍 平面结构 晶体结构 三阶非线性光学 |
| 修稿时间： | 2001年11月9日 |
Synthesis, Structure and Third-Order Nonlinear Optical Properties of a Planar Nickel Complex with Rigid Quadridentate Schiff Base Derived from S-benzyl Dithiocarbazate |
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| ZHOU Jian-Hao,WANG Yu-Xiao,CHEN Xue-Tai,SONG Ying-Lin,WENG Lin-Hong and YOU Xiao-Zeng.Synthesis, Structure and Third-Order Nonlinear Optical Properties of a Planar Nickel Complex with Rigid Quadridentate Schiff Base Derived from S-benzyl Dithiocarbazate[J].Chinese Journal of Inorganic Chemistry,2002,18(5):533-536. | |
| Authors: | ZHOU Jian-Hao WANG Yu-Xiao CHEN Xue-Tai SONG Ying-Lin WENG Lin-Hong and YOU Xiao-Zeng |
| Institution: | Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093,Department of Applied Physics, Harbin Institute of Technology, Harbin 150001,Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093,Department of Applied Physics, Harbin Institute of Technology, Harbin 150001,Department of Chemistry, Fudan University, Shanghai 200433 and Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093 |
| Abstract: | A planar metal complex NiL, H2L=acenaphthenequinone bis(S-benzyldithiocarbazate), 1, has been prepared via the template effect of nickel ion. Crystal structure of 1 was determined by X-ray diffraction analysis and shows the planar coordination configuration around the central nickel atom. Z-scan measurements show that 1 is a tran-sition metal complex exhibiting high third-order nonlinear optical effect. |
| Keywords: | nickel planar structure crystal structure third-order nonlinear optics |
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