Stabilizing effect of extractives on the photo-oxidation of Acacia confusa wood |
| |
Authors: | Tzu-Cheng Chang Chi-Lin Wu Shang-Tzen Chang |
| |
Affiliation: | a Department of Forestry and Resource Conservation, National Taiwan University, No.1, Sec. 4, Roosevelt Road, Taipei 106, Taiwan, ROC b Department of Post-Modern Agriculture, MingDao University, 369 Wen-Hua Road, Peetow, Chang Hua, 523, Taiwan, ROC |
| |
Abstract: | This study shows the photo-stabilizing effect of extractives on wood. XPS and FTIR techniques were used to analyze the variations in chemical characteristics on the surfaces of non-extracted and extracted Acacia confusa heartwood after lightfastness test. XPS survey analyses reveal that non-extracted heartwood exhibits a higher O/C ratio than the extracted wood. Furthermore, results from the detailed analysis of C1s indicated that the photo-oxidative derivatives increased in both extracted and non-extracted specimens after lightfastness test. On extracted wood, the derivatives are mainly derived from lignin, whereas extractives are the major component responsible for the generation of derivatives on non-extracted wood surface. After leaching test of UV-irradiated specimens, it was noted that the degradation products were readily removed by water. More water-soluble derivatives were leached out from the extracted wood, although higher lignin content was observed on the non-extracted wood surface. In conclusion, it is shown that photodegradation of A. confusa wood can be retarded by extractives oxidation. |
| |
Keywords: | Acacia confusa Extractives FTIR Lignin Photodegradation XPS |
本文献已被 ScienceDirect 等数据库收录! |
|