Polymer networks prepared via the crosslinking free-radical polymerization of dimethacrylate in the presence of branched polymethacrylate and its fractions |
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Authors: | S. V. Kurmaz V. V. Ozhiganov |
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Affiliation: | 1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, pr. Akademika Semenova 1, Chernogolovka, Moscow oblast, 142432, Russia
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Abstract: | The crosslinking free-radical polymerization of 1,6-hexanediol dimethacrylate in bulk in the presence of 0–40 wt % of the MMA-based branched copolymer containing more than 20 mol % divinyl comonomer, triethylene glycol dimethacrylate, is studied. It is shown that the formation of polymer networks and their structural-physical characteristics may be controlled by varying the concentration of the branched copolymer and its composition. The structural-physical characteristics of the polymers containing small amounts of the branched copolymer or narrow fractions of it are estimated from the data of sol-gel analysis and the mechanical properties of the polymers. The IR spectra of the sol and gel fractions of polydimethacry-lates containing PMMA-d8 additives demonstrate that macromolecules of the branched copolymer are incorporated into polymer networks via reactive pendant C=C bonds. |
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