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Synthesis and transformations of 1-(azidophenyl)-1H-tetrazoles
Authors:N. T. Pokhodylo  V. S. Matiichuk  N. D. Obushak
Affiliation:1. Ivan Franko Lviv National University, ul. Kirilla i Mefodiya 6, Lviv, 79005, Ukraine
Abstract:Diazotization of 1-(aminophenyl)-1H-tetrazoles and subsequent treatment of the diazonium salts with sodium azide gave 1-(azidophenyl)-1H-tetrazoles which were brought into cyclization with ethyl acetoacetate and cyanoacetanilide to obtain 1,2,3-triazole derivatives. Under these conditions, the tetrazole ring may undergo cleavage with formation of cyanamide group.
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