Resolution and assignment of the configuration of secondary aliphatic alcohols by gas chromatography on chiral phase |
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Authors: | S Binet J Dreux R Longeray |
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Institution: | (1) Laboratoire de Synthèse et de Chimie Organique Appliquée, Université Claude Bernard Lyon I, Bât. 308, 43 Bd du 11 Novembre 1918, 69622 Villeurbanne Cédex, France |
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Abstract: | Summary The study of the resolution of sixteen secondary aliphatic alcohols by gas chromatography on (+)-dodecyl (2R, 3R)-tartrate, trapping the ascending part of the peak from a conventional filled column, has allowed the determination in a single operation of the sign and order of emergence of enantiomers. A correlation between the configuration of these secondary alcohols and their order of emergence has been established. |
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Keywords: | Gas chromatography Configuration Resolution Alcohols |
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