Synthesis and structural characterization of a uranyl(VI) complex possessing unsupported unidentate thiolate ligands |
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| Authors: | Kannan Shanmugaperumal Barnes Charles L Duval Paul B |
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| Affiliation: | Department of Chemistry, University of Missouri-Columbia, 601 S. College Avenue, Columbia, Missouri 65211, USA. |
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| Abstract: | The synthesis and structural characterization of the first example of a uranyl(VI) complex possessing unsupported unidentate thiolate ligands, UO2(S-2,6-Cl2C6H3)2L2 (2b, L=N,N-diisobutylisopropylamide), are reported. Isolation of 2b as a stable mononuclear complex is provided by the alkyl substituents of the organic amide ligands, which offer enhanced solubility, electron-releasing properties, and steric protection to help saturate the uranyl(VI) coordination sphere. |
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