Organic dyes with a novel anchoring group for dye-sensitized solar cell applications |
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Authors: | Chul Baik Duckhyun Kim Moon-Sung Kang Sang Ook Kang Jaejung Ko Mohammad K. Nazeeruddin Michael Grätzel |
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Affiliation: | 1. Department of Chemistry, Korea University, Jochiwon, Chungnam 339-700, Republic of Korea;2. Energy & Environment Lab., Samsung Advanced Institute of Technology (SAIT), Yongin 446-712, Republic of Korea;3. Laboratory for Photonics and Interfaces, Institute of Chemical Sciences and Engineering, Ecole Polytechnique Fédérale de Lausanne, 1015 Lausanne, Switzerland |
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Abstract: | Two novel trialkylsilyl-containing organic sensitizers (JK-53 and JK-54) have been designed and synthesized. Nanocrystalline TiO2–silica-based dye-sensitized solar cells (DSSCs) were fabricated using these dyes. Under standard global AM 1.5 solar conditions, the JK-53-sensitized cell gave a short-circuit photocurrent density (Jsc) of 6.37 mA cm?2, an open-circuit voltage (Voc) of 0.70 V, and a fill factor of 0.74. These values correspond to an overall conversion efficiency (η) of 3.31%. By comparison, the JK-54-sensitized cell resulted in a Jsc of 7.52 mA cm?2, a Voc of 0.71 V, and a fill factor of 0.75. These values give an overall conversion efficiency of 4.01%. |
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