| 过氧杂多酸(盐)在催化有机反应中的应用 |
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| 引用本文： | 刘淑芝,邵姝媛,秦海涛,郭艳芳.过氧杂多酸(盐)在催化有机反应中的应用[J].化学通报,2012(3):239-244. |
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| 作者姓名： | 刘淑芝 邵姝媛 秦海涛 郭艳芳 |
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| 作者单位： | 东北石油大学化学化工学院石油与天然气化工省重点实验室;安东石油技术(集团)有限公司 |
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| 基金项目： | 黑龙江省杰出青年基金项目(B2004-01)资助 |
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| 摘 要： | 含活性氧的过氧杂多酸(盐)是由杂多酸(盐)与过量H2O2反应而生成的,其具有高效的催化活性,可以用于催化氧化不同的物质,是一类性能优异的绿色催化剂,其在有机合成中有十分广阔的发展前景。本文介绍了过氧杂多酸(盐)的结构、性质和催化作用,并综述了近年来其在催化有机反应中的研究进展。
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| 关 键 词： | 过氧杂多酸(盐) 过氧化氢 催化氧化 有机反应 |
Application of Peroxo-heteropolyacids(salts) in Catalytic Organic Reaction |
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| Liu Shuzhi,Shao Shuyuan,Qin Haitao,Guo Yanfang.Application of Peroxo-heteropolyacids(salts) in Catalytic Organic Reaction[J].Chemistry,2012(3):239-244. |
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| Authors: | Liu Shuzhi Shao Shuyuan Qin Haitao Guo Yanfang |
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| Institution: | 1(1College of Chemistry and Chemical Engineering,Northeast Petroleum University,Daqing 163318; 2Antonoil Oilfield Services(Group)Ltd.,Beijing 100102) |
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| Abstract: | Peroxo-heteropolyacid(salt) containing active oxygen was produced by the reaction of heteropolyacids with excess H2O2.It exhibits an interesting catalytic property and has been proved to be useful catalysts for oxidation of different organic compounds.It is a type of the green catalyst with excellent performances and will possess extensive application prospect in organic synthesis.In this paper,its structure,properties and catalysis are introduced and the progress of its catalysis in the organic reaction is reviewed. |
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| Keywords: | Peroxo-heteropolyacid(salts) Hydrogen peroxide Catalytic oxidation Organic reaction |
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