UV and X-ray-excited photoelectron spectra of trifluoromethylgermanes (CF3)4−nGeHn(n = 1–3) |
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Authors: | John E Drake Krystyna Gorzelska Reinhard Helbing Reint Eujen |
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Institution: | Department of Chemistry, University of Windsor, Ontario N9B 3P4 Canada;Anorganische Chemie, FB 9, Universität-Gesamthochschule, 5600 Wuppertal 1 W. Germany |
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Abstract: | He(I), He(II) and X-ray-excited photoelectron spectra of the trifluoromethylgermanes (CF3)4?nGeHn(n = 1–3) are reported. Assignments of the valence region are made on the basis of semi-empirical CNDO/2 calculations, comparisons with the spectra of related series of molecules, band shapes, and relative-intensity changes between features in the He(I) and He(II) spectra. Core-level binding energies are also compared with those of related species, and the usefulness of CNDO/2 and EESOP charge calculations is examined. |
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