An intramolecular Diels-Alder approach to the eunicellins: enantioselective total syntheses of ophirin B and astrogorgin |
| |
| Authors: | Crimmins Michael T Brown Brandon H Plake Hilary R |
| |
| Affiliation: | Department of Chemistry, University of North Carolina at Chapel Hill, 27599-3290, USA. crimmins@email.unc.edu |
| |
| Abstract: | The enantioselective syntheses of the eunicellins ophirin B and astrogorgin have been completed. Ring-closing metatheses provide efficient access to the oxonene rings, and highly diastereoselective intramolecular Diels-Alder reactions resulted in the formation of the hydrobenzofuran portion of the molecules. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
