Assembly of Two Isostructural Metal-organic Frameworks Based on Hetero-N,O Donor Ligand for Detecting Nitro Explosives |
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Authors: | WANG Dongmei LOU Shengjun YING Yiting GUO Zhiqi WANG Lijun |
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Institution: | Key Laboratory for Advanced Catalysis Materials, Ministry of Education, College of Chemistry and Life Sciences, Zhejiang Normal University, Jinhua 321004, P. R. China |
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Abstract: | Two isostructural metal-organic frameworks,NO3] M3(H2O)3O(TBA)3]·2DMF·6H2O(1 and 2)M=In and Fe, H2TBA=4-(1H-tetrazol-5-yl)-benzoic acid], have been successfully synthesized. Compounds 1 and 2 have three-dimensional structures bridged via the typical 6-connected tri-nuclear cluster units M3O(COO)6 and linear linker H2TBA. The whole 3D framework possesses a 6-connected acs topology. Notably, by the fluorescence technique, compound 1 can detect nitro explosives through fluorescence quenching effect, especially for 2,4,6-trinitrophenol(TNP, Ksv=3.64×104 L/mol). Furthermore, the fluorescence spectrum red shifts as the number of-NO2 group increases. Based on the aforementioned consideration, compound 1 can be considered as a potential luminescent probe for the detection of TNP. |
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Keywords: | Metal-organic framework Crystal structure Fluorescence detection Nitro explosive |
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