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Co(II) and Fe(II) phthalocyanines: synthesis,investigation of their catalytic activity towards phenolic compounds and electrochemical behaviour
Authors:Ece Tugba Saka  Zekeriya Biyiklioglu
Institution:Department of Chemistry, Faculty of Science, Karadeniz Technical University, Trabzon, Turkey
Abstract:4‐(1‐Benzylpiperidin‐4‐yl)oxy]‐substituted cobalt(II) and iron(II) phthalocyanine complexes were synthesized and their catalytic activity towards various phenolic compounds was investigated. Converting from environmentally harmful phenolic compounds into less harmful oxidation products using phthalocyanines makes this study attractive. This catalysis is feasible and time‐saving in terms of procedure and the best oxidation conditions determined. Electrochemical studies were also carried out using cyclic voltammetry and square wave voltammetry techniques. Voltammetric analyses of the synthesized phthalocyanine complexes supported their proposed structures. Copyright © 2015 John Wiley & Sons, Ltd.
Keywords:phthalocyanine  catalytic activity  phenolic compounds  cyclic voltammetry  electrochemistry
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