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A versatile method for the synthesis of diaryl and alkyl aryl ketones via palladium‐catalysed cross‐coupling reaction of arylboronic acids with acyl chlorides
Authors:Fatemeh Rafiee  Abdol R Hajipour
Institution:1. Department of Chemistry, Faculty of Science, Alzahra University, Tehran, Iran;2. Pharmaceutical Research Laboratory, Department of Chemistry, Isfahan University of Technology, Isfahan, Iran
Abstract:An efficient catalytic system using 1‐benzyl‐4‐aza‐1‐azoniabicyclo2.2.2]octane chloride and PdCl2 was developed for the cross‐coupling reaction of arylboronic acids with acyl chlorides. The catalytic amount of this homogeneous catalytic system affords the corresponding diaryl and alkyl aryl ketones in good to excellent yields under mild reaction conditions. Copyright © 2015 John Wiley & Sons, Ltd.
Keywords:palladium catalyst  cross‐coupling reaction  arylboronic acid  aryl ketone
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