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Selectivity in the electrochemical deprotection of cinnamyl groups from oxygen and nitrogen functionalities: carbonates versus carbamates |
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| Authors: | Petr Canka? Scott C Banfield |
| Institution: | a Department of Chemistry, Palacky University, Olomouc, Czech Republic b Department of Chemistry, Brock University, St. Catharines, Ont., Canada L2S 3A1 |
| Abstract: | Several cinnamyloxy carbamates and carbonates were subjected to electrochemical reduction, and the reductive fate of the cinnamyl group was investigated. Complete selectivity was observed in the removal of the cinnamyl group from oxygen versus nitrogen. |
| Keywords: | Electrochemical reduction Cinnamyloxy carbonate reductive deprotection Cinnamyloxy carbamate reductive deprotection |
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