Enantioselective synthesis of epi-(+)-Sch 642305: observation of an interesting diastereoselection during RCM |
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Authors: | Goverdhan Mehta Harish M Shinde |
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Institution: | Department of Organic Chemistry, Indian Institute of Science, Bangalore 560 012, India |
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Abstract: | In an approach towards the enantioselective total synthesis of the novel bioactive natural product Sch 642305, an unusual diastereoselection during the key RCM reaction, resulted in the synthesis of the 11-epi-isomer of Sch 642305. |
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