Catalytic properties of several supported Pd(II) complexes for Suzuki coupling reactions |
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| Authors: | Oleksiy Vassylyev |
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| Institution: | Department of Chemical and Biochemical Engineering, Rutgers, The State University of New Jersey, 98 Brett Road, Piscataway, NJ 08854, USA |
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| Abstract: | Pd(II) complexes with N-ligands were synthesized and tested for Suzuki coupling reaction. These complexes were also heterogenized on silica. The resulting site-isolated catalysts showed a high catalytic activity. The most stable complex was supported N-(propyl)ethylenediamine, which did not display any notable leaching. The effects of reaction conditions and the nature of the boronic acid derivative on the conversion of the starting compounds were studied. |
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| Keywords: | Suzuki couplings Catalysis Pd leaching |
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