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Indium tribromide-catalyzed deacetoxylation of propargylic acetate with triethylsilane
Authors:Norio Sakai  Maki Hirasawa
Affiliation:Department of Pure and Applied Chemistry, Faculty of Science and Technology, Tokyo University of Science, Noda, Chiba 278-8510, Japan
Abstract:Indium(III) bromide catalyzed the deacetoxylation of propargylic acetates with Et3SiH to produce the corresponding internal alkynes containing a variety of functional groups in good yields.
Keywords:Indium bromide   Propargylic acetate   Silane   Internal alkyne   Deacetoxylation
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