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Diastereoselective addition of silyl- and stannyl metals to γ-alkoxy-alkylidene malonates
Authors:Alain Krief  Willy Dumont
Affiliation:a Facultés Universitaires Notre-Dame de la Paix, 61 rue de Bruxelles, Namur 5000, Belgium
b Fonds pour la Formation à la Recherche dans l’Industrie et l’Agriculture, 5 rue d’Egmont, Bruxelles 1000, Belgium
Abstract:Stereochemical control of the addition of silyl- and stannyl metals to chiral γ-alkoxy-alkylidene malonates proved to be dependant on the nature of the counter ion and of the solvent but in an unpredictable way.
Keywords:1,4-Addition   Alkylidene malonates   Stannyl metals   Silyl metals   Facial stereocontrol
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