A new method for synthesis of S-aryl-O-alkyl thiolcarbonates: selenium-catalyzed reaction of alcohols with carbon monoxide and diaryl disulfides |
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| Authors: | Yutaka Nishiyama Ken Maehira |
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| Affiliation: | Department of Applied Chemistry, Faculty of Engineering, Kansai University, Suita, Osaka 564-8680, Japan |
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| Abstract: | A unique catalytic ability of selenium has been developed. When alcohols were allowed to react with diaryl disulfides in the presence of a catalytic amount of selenium under a pressurized carbon monoxide, S-aryl-O-alkyl thiolcarbonates were obtained in moderate to good yields. |
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