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A highly efficient stereoselective synthesis of (Z)- and (E)-allyl iodides from Baylis-Hillman adducts
Authors:Biswanath Das  Anjoy Majhi  Joydeep Banerjee  Nikhil Chowdhury  Katta Venkateswarlu
Institution:Organic Chemistry Division-I, Indian Institute of Chemical Technology, Hyderabad 500007, India
Abstract:A highly efficient synthesis of (Z)- and (E)-allyl iodides has been accomplished by treatment of Baylis-Hillman adducts with iodine and triphenylphosphine in methylene chloride at room temperature. The method is associated with mild reaction conditions, high yields and excellent stereoselectivity.
Keywords:Baylis-Hillman adduct  (Z)- and (E)-allyl iodides  I2/PPh3  Stereochemistry
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