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Enyne and dienyne metathesis reactions in β-carbolines
Authors:Á  lvaro Gonzá  lez-Gó  mez
Affiliation:Departamento de Química, Facultad de Farmacia, Universidad San Pablo-CEU, Urb. Montepríncipe, Boadilla del Monte, 28668 Madrid, Spain
Abstract:New indolic enynes and dienynes, based on the β-carboline system, give metathesis products with ruthenium catalysts. The synthesis of the starting materials is readily achieved from tryptamine. The tuning up of the conditions for the metathesis is discussed. Cascade metathesis gives an oxidized pentacyclic product.
Keywords:Enynes   β-Carboline   Metathesis   Cascade reactions   Ruthenium
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