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Synthesis of polyacetylenic acids isolated from Nanodea muscosa
Authors:Diego Alves
Institution:Laboratório de Síntese, Reatividade, Avaliação Farmacológica e Toxicologica de Organocalcogênios, CCNE, UFSM, Santa Maria, Rio Grande do Sul, CEP 97105-900, Brazil
Abstract:The first total synthesis of two linear polyacetylenic compounds is described. The synthesis of (E)-octadec-13-en-11-ynoic acid 1 and (E)-octadec-13-en-9,11-diynoic acid 2 by using the vinylic telluride coupling reaction was accomplished.
Keywords:Vinylic tellurides  Palladium cross-coupling  Polyacetylenes  Enynes
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