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Polymer-supported synthesis of mono-substituted porphyrins
Authors:Qifei Yang
Affiliation:Department of Chemistry, Michigan State University, East Lansing, MI 48824, USA
Abstract:Anchoring of substituted benzaldehydes to soluble and insoluble polymers allows for the synthesis of mono-substituted tetraarylporphyrins without the production of di-, tri-, and tetra-substituted porphyrin side products. The exclusion of the aforementioned side products during the synthesis of mono-substituted tetraarylporphyrin acids greatly reduced the complexity during purification of the product.
Keywords:Porphyrins   Soluble polymers   Cross-linked polymers   Mono-substituted tetraarylporphyrins
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