Chiral diamines for asymmetric synthesis: an efficient RCM construction of the ligand core of (−)- and (+)-sparteine |
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| Authors: | Bruno Danieli Daniele Passarella Alessandro Sacchetti Alessandra Silvani |
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| Institution: | Dipartimento di Chimica Organica e Industriale e Centro Interdisciplinare Studi biomolecolari e applicazioni Industriali (CISI), Università degli Studi di Milano, via G. Venezian 21, 20133 Milano, Italy |
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| Abstract: | An efficient RCM-based approach was applied to the total asymmetric synthesis of a tricyclic diamine and, formally, of its enantiomer, widely known as efficient and versatile chiral ligands of the sparteine-like type. |
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| Keywords: | RCM reactions Asymmetric synthesis Chiral ligands Sparteine |
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