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A metalation strategy for the construction of functionalized naphthalenes: the first synthesis of guieranone A
Authors:Malcolm W.B. McCulloch
Affiliation:Department of Chemistry, The Australian National University, Canberra ACT 0200, Australia
Abstract:The first synthesis of the natural product guieranone A is described, demonstrating a one-pot procedure for the synthesis of protected-1,3,6,8-tetraoxygenated naphthalenes and a subsequent directed metalation synthesis of 2-keto naphthalenes.
Keywords:Guieranone   Naphthalenes   Metalation   Natural product   Dieckmann cyclization
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