Highly enantioselective rhodium-catalyzed conjugate addition of arylboronic acids to enones at room temperature |
| |
| Authors: | Sé bastien L.X. Martina,Bart Hessen,Ben L. Feringa |
| |
| Affiliation: | Department of Organic and Molecular Inorganic Chemistry, Stratingh Institute, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The Netherlands |
| |
| Abstract: | The rhodium-phosphoramidite-catalyzed asymmetric conjugate addition of arylboronic acids to enones proceeds at room temperature using [Rh(OH)(cod)]2 or [RhCl(cod)]2/KOH as stable and readily available catalyst precursors. |
| |
| Keywords: | Asymmetric 1,4-addition Arylboronic acid Rhodium-catalysis Phosphoramidite |
| 本文献已被 ScienceDirect 等数据库收录！ |
