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Calix[4]crown in dual sensing functions with FRET
Authors:Seoung Ho Lee  Ju Han Bok  Juyoung Yoon  Jong Seung Kim
Institution:a Department of Chemistry, Dankook University, Seoul 140-714, Republic of Korea
b Department of Chemistry, Ewha Womans University, Seoul 120-750, Republic of Korea
c Cheil Industries Inc, Uiwang-si, Gyeonggi-do, 437-711, Republic of Korea
Abstract:A new calix4]crown chemosensor based on dual sensing probes reveals Pb2+ ion selectivity over other metal ions, which arises from a hypsochromic shift of azo units in UV spectrum as well as a fluorescence enhancement of pyrenyl parts in fluorescence spectrum via a suppressed FRET.
Keywords:Calixarenes  Fluorescence  Metal ion complexation
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