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Palladium-mediated transannular cyclizations of medium-ring olefinic enolsilanes |
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| Authors: | Andrew S Kende Clara E Mota Nelson |
| Institution: | a Department of Chemistry, University of Rochester, PO Box 270216, Rochester, NY 14627, USA b PPG Industries Inc., Allison Park, PA 15101, USA |
| Abstract: | Medium-ring olefinic ketone and lactone enolsilanes were subjected to palladium(II)-mediated cycloalkenylation conditions. Diverse bicyclic ring products were obtained in moderate to good yields. The effect of olefin geometry and ring size is discussed. |
| Keywords: | Palladium(II)-mediated cycloalkenylation Cyclization Medium-ring enolsilanes Bicyclic ketones/lactones |
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