| 侧基上带有C60基团的聚苯乙烯的合成 |
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| 引用本文： | 汪长春 舒昶. 侧基上带有C60基团的聚苯乙烯的合成[J]. 高等学校化学学报, 1996, 17(9): 1477-1481 |
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| 作者姓名： | 汪长春 舒昶 |
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| 作者单位： | 复旦大学高分子科学系 |
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| 摘 要： | 采用三步连续反应（氯甲基化，叠氮化，环加成反应），成功地将Ｃ６０引入聚苯乙烯的侧基上，并对每一步反应进行了较详细的讨论。
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| 关 键 词： | 氯甲基化 叠氮化 环加成反应 聚苯乙烯 碳60 |
Synthesis of Polystyrene with C_(60) in the Side Group |
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| WANG Chang-Chun,SHU Chang,FU Shou-Kuan. Synthesis of Polystyrene with C_(60) in the Side Group[J]. Chemical Research In Chinese Universities, 1996, 17(9): 1477-1481 |
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| Authors: | WANG Chang-Chun SHU Chang FU Shou-Kuan |
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| Abstract: | Three-step reactions,i.e.,chloromethylation,azidization and cycloaddition,were adopted to introduce C_(60) into the side group of polystyrene successfully, and each step reaction was discussed in detail. The products were proved to be extremely soluble in a variety of organic solvents such as CHCl3, THF, etc.. This solubility behavior is simillar to polystyrene itself and totally unlike C_(60) |
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| Keywords: | Chloromethylation Azidization Cycloaddition reaction Polystyrene C_(60) derivatives C_(60) |
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