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侧基上带有C60基团的聚苯乙烯的合成
引用本文:汪长春,舒昶.侧基上带有C60基团的聚苯乙烯的合成[J].高等学校化学学报,1996,17(9):1477-1481.
作者姓名:汪长春  舒昶
作者单位:复旦大学高分子科学系
摘    要:采用三步连续反应(氯甲基化,叠氮化,环加成反应),成功地将C60引入聚苯乙烯的侧基上,并对每一步反应进行了较详细的讨论。

关 键 词:氯甲基化  叠氮化  环加成反应  聚苯乙烯  碳60

Synthesis of Polystyrene with C_(60) in the Side Group
WANG Chang-Chun,SHU Chang,FU Shou-Kuan.Synthesis of Polystyrene with C_(60) in the Side Group[J].Chemical Research In Chinese Universities,1996,17(9):1477-1481.
Authors:WANG Chang-Chun  SHU Chang  FU Shou-Kuan
Abstract:Three-step reactions,i.e.,chloromethylation,azidization and cycloaddition,were adopted to introduce C_(60) into the side group of polystyrene successfully, and each step reaction was discussed in detail. The products were proved to be extremely soluble in a variety of organic solvents such as CHCl3, THF, etc.. This solubility behavior is simillar to polystyrene itself and totally unlike C_(60)
Keywords:Chloromethylation  Azidization  Cycloaddition reaction  Polystyrene C_(60) derivatives  C_(60)  
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