Oxidative addition of cyclic 1-oxa-5,6-ditelluraspirooctane to platinum(0) complexes |
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| Authors: | Wagner Andreas Vigo Ludmila Oilunkaniemi Raija Laitinen Risto S Weigand Wolfgang |
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| Affiliation: | University of Oulu, Department of Chemistry, P.O. Box 3000, 90014, Oulu, Finland. |
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| Abstract: | The oxidative addition of cyclic ditelluride 1-oxa-5,6-ditelluraspirooctane, Te(2)C(5)H(8)O, to bis(triphenylphosphine)(norbornene)platinum(0), [Pt(PPh(3))(2)(eta(2)-nb)], and to [1,8-bis(diphenylphosphino)naphthalene](norbornene)platinum(0), [Pt(dppn)(eta(2)-nb)], lead to the formation of dinuclear and mononuclear tellurolato platinum(ii) complexes, respectively, as a consequence of Te-Te bond cleavage; no Te-C bond cleavage was observed. |
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