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Cu(I)-catalyzed (11)C carboxylation of boronic acid esters: a rapid and convenient entry to (11)C-labeled carboxylic acids, esters, and amides |
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| Authors: | Riss Patrick J Lu Shuiyu Telu Sanjay Aigbirhio Franklin I Pike Victor W |
| Institution: | Wolfson Brain Imaging Centre, University of Cambridge, Addenbrooke's Hospital, UK. pr340@wbic.cam.ac.uk |
| Abstract: | Rapid and direct: the carboxylation of boronic acid esters with (11)CO(2) provides (11)C]carboxylic acids as a convenient entry into (11)C]esters and (11)C]amides. This conversion of boronates is tolerant to diverse functional groups (e.g., halo, nitro, or carbonyl). |
| Keywords: | boronic acid esters carbon‐11 carboxylation positron emission tomography radiochemistry |
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