丌-丌电荷转移复合物的光谱及其图解方法的探讨 |
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引用本文: | 刘昌炎,胡日恒.丌-丌电荷转移复合物的光谱及其图解方法的探讨[J].化学学报,1983,41(4):289-296. |
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作者姓名: | 刘昌炎 胡日恒 |
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作者单位: | 中国科学院化学研究所 |
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摘 要: | In this report, a method for deconvoluting the multi-band spectra of charge-transfer complex is presented and a relation between double-bands is proposed. 49 such spectra in which double-bands appear are calculated. It has been found that the deviation between the calculated and the measured values is less than 3%. The scheme can be extended to deconvolute the CT peaks are used to evaluate the electron affinities of these acceptors. But, the scheme can be used to the π-π charge-transfer complexes.
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关 键 词: | 测定 分解 电荷转移络合物 谱图 |
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