Mechanochemical Reaction of 1,10-Phenanthroline with Metallic Iron |
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| Authors: | Drozdova M. K. Myakishev K. G. Ikorskii V. N. Aksenov V. K. Volkov V. V. |
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| Affiliation: | (1) Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent'eva 3, Novosibirsk, 630090, Russia |
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| Abstract: | Fe(II) complex is isolated from the products of mechanical activation of a mixture of the powdered carbonyl Fe and 1,10-phenanthroline. According to the data of elemental analysis, an electronic absorption spectra, magnetochemical and EPR studies, the isolated compound is [FePhen3]2+ Phen–OH– · 3H2O that contains Phen– radical-anion. |
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