Study on the ionic conductivity of polyether network polymer electrolytes: effect of the preparation method |
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| Affiliation: | 1. Institutes of Physical Science and Information Technology, Key Laboratory of Structure and Functional Regulation of Hybrid Materials of Ministry of Education, Anhui University, Hefei 230601, China;2. CAS Key Laboratory of Soft Matter Chemistry, Department of Polymer Science and Engineering, University of Science and Technology of China, Hefei 230026, China;1. Department of Clinical Epidemiology, Grenoble Alps University Hospital, TIMC-IMAG Laboratory, UMR 5525 CNRS, Grenoble Alps University, France;2. University hospital of Grenoble-Alpes, Grenoble, France;3. Department of Nursing Education, Centre Hospitalier Alpes Isère, France;4. UVSQ, Inserm, Anti-Infective Evasion and Pharmacoepidemiology, University of Paris-Saclay, Montigny le Bretonneux, France;5. Epidemiology and Public Health Department, AP-HP, University of Paris-Saclay, Paris, France;6. Laboratoire DIPHE, Université Lumière Lyon 2, France;7. Institut Universitaire de France, Paris, France |
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| Abstract: | In preparing the network polymer electrolytes, two different methods were taken in the incorporation of salt into the polymer network. In one method, the network polyether was dipped into the lithium salt solution with or without plasticizer, and in the other method the network formation was proceeded in the presence of the lithium salt in the reaction medium with or without plasticizer. We designated the former as the network polymer electrolyte (NPE), the latter as the salt added network polycondensate electrolyte (SNPE). For the NPEs, the ionic conductivities increased with decreasing the cross-linking degree, which was mainly attributed to the increase of the free ion fraction with the decrease in the cross-linking degree that was evidenced by 7Li NMR relaxation studies. For the NPEs plasticized with MPEG7, the conductivities increased with increase of the MPEG7 content, which was largely due to the increase of the mobility of the free ions. The ionic conductivity of the SNPE was higher than that of the NPE, which resulted from the lower microviscosity of the SNPE due to the larger amount of the contained linear polyether and the lower cross-linking degree. |
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