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二烷基氨荒酸二苯基锗盐的合成及性质研究
引用本文:张如芬,朱德中,尹汉东,马春林.二烷基氨荒酸二苯基锗盐的合成及性质研究[J].无机化学学报,2002,18(4):386-388.
作者姓名:张如芬  朱德中  尹汉东  马春林
作者单位:聊城师范学院化学系,聊城,252059
基金项目:高等学校骨干教师资助计划项目(No.2050),山东省自然科学基金资助项目(No.Y2000B08)。
摘    要:The diphenylgermanium bis-dithiocarbamates Ph2Ge(S2CR)2 (I~VIII) have been synthesized by the reaction of Ph2GeCl2 with RCS2Na in CH2Cl2 solvent. Their structures were characterized with IR, 1H NMR, UV spectra and the in vitro antitumour activity are tested. In mentioned germanium complexes (I~VIII) the dithiocarbamatyl groups are monodentate ligands.

关 键 词:二苯基锗  氨荒酸盐  合成  抗癌活性

Synthesis and Properties of Diphenylgermanium Bis-Dithiocarbamates
ZHANG Ru-Fen,ZHU De-Zhong,YIN Han-Dong and MA Chun-Lin.Synthesis and Properties of Diphenylgermanium Bis-Dithiocarbamates[J].Chinese Journal of Inorganic Chemistry,2002,18(4):386-388.
Authors:ZHANG Ru-Fen  ZHU De-Zhong  YIN Han-Dong and MA Chun-Lin
Institution:Department of Chemistry, Liaocheng Teachers University, Liaocheng 252059,Department of Chemistry, Liaocheng Teachers University, Liaocheng 252059,Department of Chemistry, Liaocheng Teachers University, Liaocheng 252059 and Department of Chemistry, Liaocheng Teachers University, Liaocheng 252059
Abstract:The diphenylgermanium bis-dithiocarbamates Ph2Ge(S2CR)2 (Ⅰ~Ⅷ) have been synthesized by the reaction of Ph2GeCl2 with RCS2Na in CH2Cl2 solvent.Their structures were characterized with IR,1H NMR,UV spectra and the in vitro antitumour activity are tested.In mentioned germanium complexes (Ⅰ~Ⅷ) the dithiocarbamatyl groups are monodentate ligands.
Keywords:diphenylgermanium  dithiocarbamate  synthesis  antitumour activity
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