| 钯催化羰基衍生物α位的芳基化反应及其在天然产物合成中的应用 |
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| 引用本文： | 邵志会,张洪彬.钯催化羰基衍生物α位的芳基化反应及其在天然产物合成中的应用[J].有机化学,2005,25(3):282-289. |
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| 作者姓名： | 邵志会 张洪彬 |
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| 作者单位： | 云南大学,药学院,昆明,650091 |
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| 摘 要： | 对钯催化羰基衍生物α位的芳基化反应的研究进展做了论述, 重点介绍了酮羰基化合物α-芳基化反应、酰胺类化合物α-芳基化反应和酯类化合物α-芳基化反应的研究进展. 此外, 对钯催化酮α-芳基化反应在γ-Lycorane合成中的应用和钯催化酰胺α-芳基化反应在Cherylline, Latifine及Physovenine等天然产物合成中的应用也进行了专门介绍.
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| 关 键 词： | 钯催化 酮 酰胺 酯 α-芳基化 天然产物 合成 应用 |
| 收稿时间： | 2004-2-25 |
| 修稿时间： | 2004年2月25日 |
Palladium-Catalyzed α-Arylation of Carbonyl Derivatives and Its Applications in the Synthesis of Natural Products |
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| SHAO Zhi-Hui,ZHANG Hong-Bin.Palladium-Catalyzed α-Arylation of Carbonyl Derivatives and Its Applications in the Synthesis of Natural Products[J].Chinese Journal of Organic Chemistry,2005,25(3):282-289. |
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| Authors: | SHAO Zhi-Hui ZHANG Hong-Bin |
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| Institution: | (School of Pharmacy, Yunnan University, Kunming 650091 |
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| Abstract: | The progress in palladium-catalyzed α-arylation of carbonyl derivatives is reviewed with emphasis on α-arylation of ketones, amides and esters. The applications of α-arylation of ketones in the synthesis of γ-Lycorane as well as α-arylation of amides in the synthesis of natural products including cherylline, latifine and physovenine are also described. |
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| Keywords: | palladium-catalyzed ketone amide ester α-arylation natural product syn-thesis application |
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