| 表面活性剂和助表面活性剂对镍的缓蚀作用 |
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| 引用本文： | 刘天晴,邹爱华,郭荣.表面活性剂和助表面活性剂对镍的缓蚀作用[J].物理化学学报,2000,16(10):899-905. |
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| 作者姓名： | 刘天晴 邹爱华 郭荣 |
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| 作者单位： | Department of Chemistry,Yangzhou University,Yangzhou 225002 |
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| 基金项目： | 国家自然科学基金资助项目!(29733110) |
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| 摘 要： | 在ＨＣｌ水溶液中，三种典型的表面活性剂（ＣＴＡＢ、ＳＤＳ和Ｔｒｉｔｏｎ Ｘ－１００）对镍均有缓蚀作用，其缓蚀效率、腐蚀活化能的大小顺序是：ＣＴＡＢ〉Ｔｒｉｔｏｎ ｘ－１００〉ＳＤＳ。助表面活性剂正丁醇可作为缓蚀调节剂，其加入可控制金属镍在ＨＣｌ水溶液中的腐蚀速率。金属镍在各介质中腐蚀速率的顺序为ＨＣｌ（ａｑ）〉知性剂＋丁醇＋ＨＣｌ（ａｑ）〉表面活性剂＋ＨＣｌ（ａｑ）〉表面活性剂＋丁醇（ａｑ）〉表面
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| 关 键 词： | 镍 表面活性剂 正丁醇 腐蚀 |
| 收稿时间： | 2000-02-12 |
| 修稿时间： | 2000-04-01 |
Effect of Surfactant and Cosurfactant on the Protecting Corrosion for Nickel |
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| Liu Tianqing,Zou Aihua,Guo Rong.Effect of Surfactant and Cosurfactant on the Protecting Corrosion for Nickel[J].Acta Physico-Chimica Sinica,2000,16(10):899-905. |
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| Authors: | Liu Tianqing Zou Aihua Guo Rong |
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| Institution: | Department of Chemistry,Yangzhou University,Yangzhou 225002 |
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| Abstract: | The corrosion of Ni in HCl(aq) solution can be inhibited in three typical surfactant systems. The order of the inhibition efficiency and the corrosive active energy is CTAB > Triton X-100 > SDS. The cosurfactant butanol can be used as inhibiting adjuster, and can control and change the corrosive rate of Ni in HCl(aq)solution. The order of the corrosive rate in different medium is HCl(aq) > surfactant＋ butanol＋ HCl (aq) > surfactant＋ HCl(aq) > surfactant＋ butanol(aq) >surfactant(aq). |
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| Keywords: | Nickel Surfactant n-Butanol Corrosion |
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