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无长链席夫碱衍生物单分子膜和LB膜
引用本文:蔡俊放,刘鸣华,李津如,江龙.无长链席夫碱衍生物单分子膜和LB膜[J].物理化学学报,2000,16(7):583-586.
作者姓名:蔡俊放  刘鸣华  李津如  江龙
作者单位:Laboratory Colloid and Interface Science,Center for Molecular Science,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100080
摘    要:在银离子的诱导下,两种含有苯并咪唑、没有长链取代基的席夫碱衍生物可以形成稳定的单分子膜,此单子分子膜可以用水平拉膜法转移到固体表面形成LB膜、LB膜的紫外吸收光谱和光电子能谱研究表明,Ag(Ⅰ)离子被络合进行了单分子膜中。

关 键 词:席夫碱  单分子膜  LB膜  非典型两亲分子  
收稿时间:2000-02-28
修稿时间:2000-04-07

Monolayers and Langmuir-Blodgett Films of Benzimidazole-containing Schiff Bases without Substituted Alkyl Chain
Cai Junfang,Liu Minghua,Li Jinru,Jiang Long.Monolayers and Langmuir-Blodgett Films of Benzimidazole-containing Schiff Bases without Substituted Alkyl Chain[J].Acta Physico-Chimica Sinica,2000,16(7):583-586.
Authors:Cai Junfang  Liu Minghua  Li Jinru  Jiang Long
Institution:Laboratory Colloid and Interface Science,Center for Molecular Science,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100080
Abstract:Two benzimidazole-containing Schiff bases 2 (2′-hydroxybenzylidene)-aminobenzimi-dazole (HBA) and 2-(2′-hydroxynaphthylidene)-aminobenzimidazole (HNA),which have no substituted alkyl chains, have been found to form stable monolayers at the air/water interface in the presence of Ag(I) ion in the subphase. It has been found from UV-vis spectra and XPS measurements that the complex formation between the Schiff bases with Ag(I) ion induced the monolayer formation.
Keywords:Schiff Base    Monolayer    Langmuir  Blodgett Film    Non  typical amphiphile
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