Synthesis and structure of 6-azido-2,4-bis(2,2,2-trinitroethylamino)-1,3,5-triazine and its <Emphasis Type="Italic">N</Emphasis>-nitro derivatives |
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| Authors: | A G Korepin A V Shastin G V Lagodzinskaya G V Shilov D V Korchagin N M Glushakova V S Malygina V P Kosilko V P Lodygina S M Aldoshin |
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| Institution: | 1.Institute of Problems of Chemical Physics,Russian Academy of Sciences,Chernogolovka,Moscow Region,Russian Federation |
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| Abstract: | Methods were developed for the synthesis of 6-azido-2,4-bis(2,2,2-trinitroethylamino)- 1,3,5-triazine and its N-nitro derivatives (6-azido-2,4-bis(2,2,2-trinitroethyl)nitramino-1,3,5-triazine and 6-azido-2-(2,2,2-trinitroethylamino)-4-(2,2,2-trinitroethyl)nitramino-1,3,5-triazine) containing combinations of azido, trinitroethyl, and nitramine groups. These compounds are of interest as components of energetic composites. The molecular and crystal structures of 6-azido-2,4-bis(2,2,2-trinitroethylamino)-1,3,5-triazine and 6-azido-2,4-bis(2,2,2-trinitroethyl) nitramino-1,3,5-triazine were studied by X-ray diffraction and NMR spectroscopy. |
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